模拟退火法在吸收薄膜的椭偏反演算法中的应用

将一种广泛用于求解复杂系统优化问题的技术－－模拟退火法－－用来求解椭偏反演方程。首先假设一个薄膜模型，计算出其相应的椭偏参数（Ψ，Δ）的值，在这个计算值的基础上加入不同标准偏差的高斯噪声；然后将加入噪声后的值（Ψm,Δm)作为模拟的测量数据，采用模拟退火算法进行求解，验证得知这种方法求得的薄膜参数很接近于假设的薄膜模型参数的真值，与其他文献的报道结果一致，而且在扩大搜寻范围时，仍然可以得到准确解，从而证明了该方法的可行性以及有效性。     

(Ni0.81Fe0.19)1-xCrx作为种子层对NiFe/FeMn交换偏置的影响

采用一种新的种子层材料:(Ni081Fe019)1-xCrx,通过改变种子层中Cr原子的含量,使得在其上生长的NiFeFeMn双层膜的织构和晶粒尺寸产生极大的差异,系统研究了NiFeFeMn双层膜中FeMn晶粒尺寸和织构对交换偏置的影响.实验结果表明,在FeMn的γ相(111)织构较好的前提下,交换偏置场的大小与织构的差异没有关系;FeMn的晶粒尺寸对交换偏置场有很大影响,较小的反铁磁层晶粒对交换偏置场有利,过大的反铁磁层晶粒不利于交换偏置场.将(Ni081Fe019)05Cr05与传统的种子层材料Ta进 关键词： 交换偏置 晶粒尺寸 织构 种子层     

Bipyridinophane‐containing conjugated polymers modulated with an intramolecular aromatic C?H/π interaction

Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and ¹H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu²⁺, Co²⁺, Ni²⁺, Zn²⁺, Mn²⁺, and Ag⁺ ions. In contrast, only Cu²⁺, Co²⁺, and Ni²⁺ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu²⁺, Co²⁺, and Ni²⁺ ions toward P7 are of the order of 10⁶ M^?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006     

拟南芥胚的不同区域对MeV离子辐照的响应

利用不同能量的质子在大气环境中辐照拟南芥的含水种子，能量从1.1MeV到6.5MeV.根据模拟计算结果，相应能量的离子对种子的损伤区域分别为胚的浅层、胚的一半和整个胚.本实验中，具有较高能量的质子可以完全均匀地作用于拟南芥生长、发育及遗传密切相关的胚茎端分生组织，而能量较低的质子则不能直接作用于茎端分生组织.实验所用质子注量范围为4×10⁹ions/cm²—1×10¹⁴ions/cm².实验结果显示，虽然拟南芥种子的发芽率和幼苗存活率随离子注量增加都呈现下降的趋势，但对应于不同的胚损伤区域，即在不同的入射质子能量条件下，注量曲线具有各自的特征.实验结果显示，拟南芥种子中除了胚茎端分生组织作为对离子辐照敏感的辐射主靶外，茎端分生组织之外的胚区域可能作为离子辐射次靶，影响到最终的辐射生物学效应. 关键词： 离子辐照 拟南芥 胚区域 生物效应     

Mössbauer studies in an external field of well-crystallized Al-maghemites made from hematite

A series of hematites with up to 15 mol% Al substitution was converted to maghemites by reduction in the presence of organic matter, followed by slow oxidation. The maghemites formed were studied by Mössbauer spectroscopy in an external field of 60 kOe at 4 K. This technique allows the determination of site occupancy as well as the canting angle. The spectra are in agreement with a model having both vacancies and Al only in the octahedral sites and small canting angles for both sites. A small dipolar field at the tetrahedral sites was required to fit the line shape. The data indicate that about 10 mol% Al may be a solubility limit in maghemite.     

Quantum Cosmology in CGBD Theory

We apply the theory developed in quantum cosmology to a model of charged generalized Brans–Dicke gravity. This is a quantum model of gravitation interacting with a charged Brans–Dicke type scalar field which is considered in the Pauli frame. The Wheeler–DeWitt equation describing the evolution of the quantum Universe is solved in the semiclassical approximation by applying the WKB approximation. The wave function of the Universe is also obtained by applying both the Vilenkin-like and the Hartle–Hawking-like boundary conditions. We then make predictions from the wave functions and infer that the Vilenkin's boundary condition is more reasonable in the Brans–Dicke gravity models leading a large vacuum energy density at the beginning of the inflation.     

Creation of multiquantum coherences from equilibrium spin systems

Recently it has been suggested that zero quantum coherence in scalar coupled spin systems at thermal equilibrium can be created by a single non-selective pulse. In this note, it is shown that the proposed effect will be masked as a consequence of the failure of the conventional high-temperature approximation normally applied to the equilibrium spin density operator. For exacting experiments, its appears that the approximation (eq) ≈ 1-H /kT may not suffice.     

Crystallographic report: Bis[bis(N,N‐dibenzyldithiocarbamato)cadmium(II)]

The centrosymmetric structure of {Cd[S₂CN(CH₂Ph)₂]₂}₂ features both bridging and chelating dithiocarbamate ligands so that a square pyramidal S₅ coordination geometry results. Copyright © 2004 John Wiley & Sons, Ltd.     

Optimally Dense Packings of Hyperbolic Space

In previous work, a probabilistic approach to controlling difficulties of density in hyperbolic space led to a workable notion of optimal density for packings of bodies. In this paper we extend an ergodic theorem of Nevo to provide an appropriate definition of those packings to be considered optimally dense. Examples are given to illustrate various aspects of the density problem, in particular the shift in emphasis from the analysis of individual packings to spaces of packings.     

On a dynamic fractional game

Consider a two-person zero-sum game constructed by a dynamic fractional form. We establish the upper value as well as the lower value of a dynamic fractional game, and prove that the dual gap is equal to zero under certain conditions. It is also established that the saddle point function exists in the fractional game system under certain conditions so that the equilibrium point exists in this game system.